Preheat oven to 425 degrees F. Trim ends of broccoli crowns. Cut off florets. Peel outer layer from stems and discard. Cut stems into 1/2" slices. Toss broccoli with 2 tablespoons oil. Season with salt and pepper.
In a small bowl, combine bread crumbs, Parmesan, and remaining 1 tablespoon oil. Arrange pork chops on a large rimmed baking sheet and season all over with salt and pepper. Brush tops of pork chops with mustard. Spoon 2 tablespoons crumb mixture onto each pork chop, spreading in even layer.
Arrange broccoli around pork chops. Bake 25 minutes, until pork chops are cooked through (145 degrees F) and broccoli is tender.
Hannaford fresh Magazine, September 2023